Organic Chemistry Alkanes

Alkanes: Naming, Properties and Drawing Chemical Structures

Topic overview

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Open-chain alkanes have the general formula CₙH₂ₙ₊₂. Their names are based on the number of carbons in the longest continuous chain, with numbering chosen to give substituents the lowest locants; repeated substituents and cycloalkanes follow additional naming conventions. Alkanes can be represented with line-angle, condensed, expanded, Newman, and wedge-dash drawings. Their nonpolar character makes them hydrophobic and insoluble in water. Physical state and boiling point vary with chain length and branching. Although alkanes are generally relatively unreactive, the topic introduces combustion, free-radical halogenation, and cracking, including the possibility of carbon monoxide or soot during incomplete combustion.

Learning objectives

What you'll learn

  • Identify the general formula and structural features of open-chain alkanes.
  • Select and number a parent chain when naming branched alkanes.
  • Apply substituent, repeated-group, and cycloalkane naming conventions.
  • Relate alkane polarity, chain length, and branching to physical properties.
  • Recognize common structural representations and key alkane reactions.
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